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Dieter Weber, T. David Jones, Laura L. Adduci and Prof. Dr. Michel R. Gagné Strong Electronic and Counterion Effects on Geminal Digold Formation and Reactivity as Revealed by Gold(I)–Aryl Model Complexes Angewandte Chemie International Edition 51

Article first published online: 25 JAN 2012 | DOI: 10.1002/anie.201107659

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Geminal diauration of [Ph3PAu(aryl)] complexes has been investigated to model the intermediacy of geminally diaurated gold(I)–vinyl complexes in catalysis (see scheme). The results advance our understanding of the factors influencing the stability, reactivity, and dynamics of these organometallic intermediates.

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