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Dr. Zhen-an Qiao, Dr. Suree S. Brown, Dr. Jamie Adcock, Dr. Gabriel M. Veith, Dr. J. Chris Bauer, Dr. E. Andrew Payzant, Dr. Raymond R. Unocic and Dr. Sheng Dai A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides Angewandte Chemie International Edition 51

Article first published online: 6 FEB 2012 | DOI: 10.1002/anie.201107812

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F tactic: Highly fluorine-doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.

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