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Prof. Dr. Zhikun Wu Anti-Galvanic Reduction of Thiolate-Protected Gold and Silver Nanoparticles Angewandte Chemie International Edition 51

Article first published online: 1 FEB 2012 | DOI: 10.1002/anie.201107822

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Unexpected: Anti-galvanic reduction (AGR), that is, metal ions are reduced by more-noble metals, was found in small thiolated gold (see figure) and silver nanoparticles! These findings are not only unexpected considering the classic galvanic theory, but also provide a facile and mild method to make alloys on the nanoscale or tune the compositions, structures, and properties of nanostructures that are otherwise difficult to obtain.

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