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Dipl.-Chem. Frank Maier and Prof. Dr. Oliver Trapp Effects of the Stationary Phase and the Solvent on the Stereodynamics of biphep Ligands Quantified by Dynamic Three-Column HPLC Angewandte Chemie International Edition 51

Article first published online: 9 FEB 2012 | DOI: 10.1002/anie.201107907

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Dynamics and kinetics in a single stroke: The stereodynamics of the tropos-chiral diphosphine biphep and its 3,3′-dialkoxy analogues were investigated by enantioselective dynamic HPLC (DHPLC) and a novel three-column approach, in with the dynamics and kinetics of the interconversion were examined in a single experimental setup (see scheme).

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