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María Ballesteros-Rivas, Dr. Hanhua Zhao, Dr. Andrey Prosvirin, Eric W. Reinheimer, Rubén A. Toscano, Prof. Jesús Valdés-Martínez and Prof. Kim R. Dunbar Magnetic Ordering in Self-assembled Materials Consisting of Cerium(III) Ions and the Radical Forms of 2,5-TCNQX2 (X=Cl, Br) Angewandte Chemie International Edition 51

Version of Record online: 8 MAY 2012 | DOI: 10.1002/anie.201107938

Thumbnail image of graphical abstract

Ribbon-like coordination polymers composed of CeIII ions and TCNQX2 (TCNQ=tetracyanoquinodimethane; X=Cl, Br), but not TCNQ radicals, show unexpected magnetic ordering (see picture; Ce green). This behavior reveals remarkable subtlety for magnetic properties of lanthanide–organic materials.

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