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Dr. Gary M. Noonan, Dr. José A. Fuentes, Dr. Christopher J. Cobley and Dr. Matthew L. Clarke An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes Angewandte Chemie International Edition 51

Article first published online: 27 JAN 2012 | DOI: 10.1002/anie.201108203

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Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH[DOUBLE BOND]CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.

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