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Dipl.-Chem. Christian Logemann, Prof. Dr. Thorsten Klüner and Prof. Dr. Mathias S. Wickleder The Elusive Tetrasulfate Anion [S4O13]2− Angewandte Chemie International Edition 51

Version of Record online: 4 APR 2012 | DOI: 10.1002/anie.201108206

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Sulfates united: The unique tetrasulfate S4O132− anion was observed in the structure of (NO2)2[S4O13] that forms in the reaction of N2O5 with SO3. Theoretical investigations show that the anion is a stable member of the polysulfate series [SnO3n+1]2−, which was investigated up to n=11.

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