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Reed T. Larson, Michael D. Clift and Prof. Regan J. Thomson Total Synthesis of the Galbulimima Alkaloid (−)-GB17 Angewandte Chemie International Edition 51

Version of Record online: 27 JAN 2012 | DOI: 10.1002/anie.201108227

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A tale of two Michaels: The first enantioselective total synthesis of (−)-GB17 is reported. Construction of this unique naphthoquinolizinone skeleton was achieved by two stereoselective intramolecular Michael additions, one under catalyst control and the other under substrate control.

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