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Prof. Masamichi Ogasawara, Dr. Wei-Yi Wu, Sachie Arae, Dr. Susumu Watanabe, Tomotaka Morita, Prof. Tamotsu Takahashi and Prof. Ken Kamikawa Kinetic Resolution of Planar-Chiral (η6-Arene)Chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis Angewandte Chemie International Edition 51

Article first published online: 3 FEB 2012 | DOI: 10.1002/anie.201108292

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Molybdenum-catalyzed asymmetric ring-closing metathesis has been used for the kinetic resolution of racemic planar-chiral (η6-arene)chromium complexes with excellent enantioselectivity. The products are excellent precursors for the synthesis of various planar-chiral (η6-arene)chromium derivatives and can also be applied as chiral ligands in rhodium-catalyzed asymmetric reactions.

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