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Dr. Lantao Liu, Dr. Naoki Ishida and Prof. Dr. Masahiro Murakami Atom- and Step-Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon–Carbon Bond Cleavage Angewandte Chemie International Edition 51

Article first published online: 27 JAN 2012 | DOI: 10.1002/anie.201108446

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In the nick of time: A nickel-catalyzed asymmetric intramolecular alkene insertion reaction into cyclobutanones (1) has been developed. The reaction significantly reduces the number of steps required for the synthesis of chiral benzobicyclo[2.2.2]octenones (2).

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