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Dr. Florie Lavigne, Dr. Eddy Maerten, Dr. Gilles Alcaraz, Prof. Vicenç Branchadell, Dr. Nathalie Saffon-Merceron and Dr. Antoine Baceiredo Activation of CO2 and SO2 by Boryl(phosphino)carbenes Angewandte Chemie International Edition 51

Version of Record online: 27 JAN 2012 | DOI: 10.1002/anie.201108452

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Dismembering molecules: The stable boryl(phosphino)carbene 1 can cleave small organic dioxide molecules. With CO2 and SO2, 1 gives, respectively, the phosphacumulene ylide [Mes(iPr2N)B-O-P(CCO)(NiPr2)Mes] (see scheme and structure) and boryl(phosphoryl)sulfine [Mes(iPr2N)B-C(SO)-P(O)(NiPr2)Mes] which have been structurally and spectroscopically characterized.

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