E-mail

E-mail a Wiley Online Library Link

Dr. Stuart E. Smith, Dr. Jenny Y. Yang, Dr. Daniel L. DuBois and Dr. R. Morris Bullock Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic Angewandte Chemie International Edition 51

Version of Record online: 14 FEB 2012 | DOI: 10.1002/anie.201108461

Thumbnail image of graphical abstract

An efficient ligand combination: A new bis(diphosphine) nickel(II) complex (see picture) is described. A ΔG° value of 0.84 kcal mol−1 for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displayed reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, which are characteristic for hydrogenase enzymes.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH