Dr. Wei Liu, Anne-Kristin Herrmann, Dr. Dorin Geiger, Lars Borchardt, Dr. Frank Simon, Prof. Stefan Kaskel, Dr. Nikolai Gaponik and Prof. Alexander Eychmüller High-Performance Electrocatalysis on Palladium Aerogels Angewandte Chemie International Edition 51
Nanostructures as catalysts: Pd aerogels modified with α-, β-, and γ-cyclodextrins can be obtained by the spontaneous self-assembly of in situ generated Pd nanoparticles. The Pd aerogels show excellent electrocatalytic activity for the oxidation of ethanol. The catalytic activity is believed to arise from the nonsupported nanometer-scale structure of the aerogel network and the interactions of ethanol with the cyclodextrin.
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