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M. Sc. Jörn Bruns, Dipl.-Chem. Matthias Eul, Prof. Dr. Rainer Pöttgen and Prof. Dr. Mathias S. Wickleder Cover Picture: Octahedral Pd2+ Coordination and Ferromagnetic Ordering in Pd(S2O7) (Angew. Chem. Int. Ed. 9/2012) Angewandte Chemie International Edition 51

Version of Record online: 16 DEC 2011 | DOI: 10.1002/anie.201108616

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Oxidation of elemental palladium ;at elevated temperatures leads to the blue disulfate Pd(S2O7), which has an octahedral and not the usual square-planar coordination of a Pd2+ center. In their Communication on page 2204 ff., M. S. Wickleder, R. Pöttgen, and co-workers show that this rare coordination leads to paramagnetic behavior and that ferromagnetic ordering occurs at low temperature. This is the first example for this phenomenon in an oxidic Pd2+ compound.

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