Chao Chen, Yan Xie, Lingling Chu, Dr. Ruo-Wen Wang, Prof. Dr. Xingang Zhang and Prof. Dr. Feng-Ling Qing Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur Angewandte Chemie International Edition 51
Fluorinated functionality: The copper-catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with TMSCF3 and elemental sulfur at room temperature is described for the first time. This reaction provides a concise and efficient method for the synthesis of aryl trifluoromethyl thioethers (ArSCF3) under mild conditions. Phen=Phenanthroline.
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