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Dr. Quentin Raffy, David-Alexandre Buisson, Dr. Jean-Christophe Cintrat, Dr. Bernard Rousseau, Dr. Serge Pin and Dr. Jean Philippe Renault Carbon-Centered Radicals Can Transfer Hydrogen Atoms between Amino Acid Side Chains Angewandte Chemie International Edition 51

Article first published online: 6 FEB 2012 | DOI: 10.1002/anie.201108856

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Radical migration between aliphatic amino acid side chains can occur in solution and intramolecularly in peptides. The kinetic constant of the hydrogen transfer reaction was measured by using competition kinetics, and the half-life as well as the distance that a radical can move within a protein was calculated.

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