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Dr. Julien Kelber, Dr. Marie-France Achard, Dr. Fabien Durola and Dr. Harald Bock Distorted Arene Core Allows Room-Temperature Columnar Liquid-Crystal Glass with Minimal Side Chains Angewandte Chemie International Edition 51

Article first published online: 12 APR 2012 | DOI: 10.1002/anie.201108886

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Atropoisomeric aromatic cores enhance disorder inside the supramolecular packing of disk-shaped mesogens. Core-extension of perylene with an atropoisomeric [4]helicene fragment thus gives rise to a room-temperature liquid crystal even with extremely short side chains. Replacement of diester moieties by imide substituents allows switching from donor- to acceptor-type electronic characteristics.

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