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Dr. Emilio J. Cocinero, Prof. Alberto Lesarri, Dr. Patricia Écija, Dr. Francisco J. Basterretxea, Prof. Jens-Uwe Grabow, Dr. José A. Fernández and Prof. Fernando Castaño Inside Cover: Ribose Found in the Gas Phase (Angew. Chem. Int. Ed. 13/2012) Angewandte Chemie International Edition 51

Article first published online: 17 JAN 2012 | DOI: 10.1002/anie.201109101

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Sugars in space: The rotational signature of ribose, the first C5 sugar to be detected in the gas phase, is reported by E. J. Cocinero, A. Lesarri, and co-workers in their Communication on page 3119 ff. Six conformers were detected by a combination of laser vaporization and microwave spectroscopy. All adopt a pyranoside (pyr) structure, stabilized by cooperative hydrogen-bond networks, rather than the furanose form usually found in biological compounds. This rotational spectrum opens the door to the radio-astronomical detection of the first sugar in space.

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