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Dr. Paul Benndorf, Sophia Schmitt, Dr. Ralf Köppe, Dr. Pascual Oña-Burgos, Dr. Andreas Scheurer, Prof. Dr. Karsten Meyer and Prof. Dr. Peter W. Roesky Catching Gaseous SO2 in Cone-Type Lanthanide Complexes: An Unexpected Coordination Mode for SO2 in f-Element Chemistry Angewandte Chemie International Edition 51

Version of Record online: 4 APR 2012 | DOI: 10.1002/anie.201109109

Thumbnail image of graphical abstract

Easy come, easy go: The first molecular SO2 complexes of the lanthanides (Ln=Sm, Eu) have been prepared. The compounds can reversibly coordinate gaseous SO2. Concomitant with the addition and removal of SO2, the color of the complexes changes reversibly (see scheme). The structures of the SO2 compounds could be confirmed in solution and in the solid state.

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