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Dr. Keishi Ishida, Thorger Lincke and Prof. Dr. Christian Hertweck Assembly and Absolute Configuration of Short-Lived Polyketides from Burkholderia thailandensis Angewandte Chemie International Edition 51

Version of Record online: 19 APR 2012 | DOI: 10.1002/anie.201200067

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Decoded before decay: Cryptic and highly unstable polyketide metabolites, thailandamides A and B, were isolated from Burkholderia thailandensis, and their absolute configurations fully elucidated using a combination of chemical degradation, bioinformatics, NMR spectroscopy, precursor-directed biosynthesis, and analysis of pathway intermediates (see scheme).

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