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Subhendu Roy, Prof. Dr. Eluvathingal D. Jemmis, Prof. Dr. Axel Schulz, Dr. Torsten Beweries and Prof. Dr. Uwe Rosenthal Theoretical Evidence of the Stabilization of an Unusual Four-Membered Metallacycloallene by a Transition-Metal Fragment Angewandte Chemie International Edition 51

Version of Record online: 23 APR 2012 | DOI: 10.1002/anie.201200148

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Connect five: Theoretical studies reveal that a Group 4 metal can significantly stabilize an unusual four-membered metallacycloallene. The role of the substituents R that donate two electrons to the complex is decisive. The systems contain an unprecedented crucial M[BOND]C bond in the MC3 ring (see scheme; Cp=cyclopentadienyl, NHC=N-heterocyclic carbene).

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