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Dr. Harshita Kumari, Dr. Steven R. Kline, Dr. Wei G. Wycoff, Dr. Rick L. Paul, Andrew V. Mossine, Prof. Carol A. Deakyne and Prof. Jerry L. Atwood Solution-Phase Structures of Gallium-Containing Pyrogallol[4]arene Scaffolds Angewandte Chemie International Edition 51

Version of Record online: 18 APR 2012 | DOI: 10.1002/anie.201200209

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Hollow cylinders: Gallium- and gallium–zinc-seamed pyrogallol[4]arene nanoassemblies were studied in the solution phase through various methods. The results reveal their rearrangement from spheres in the solid state to toroids in solution (see, for example, PgC4GaZn) illustrating the structural flexibility of gallium in the metal-seamed frameworks.

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