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Dr. Bo Liu, Dr. Thierry Roisnel, Prof. Dr. Jean-François Carpentier and Dr. Yann Sarazin When Bigger Is Better: Intermolecular Hydrofunctionalizations of Activated Alkenes Catalyzed by Heteroleptic Alkaline Earth Complexes Angewandte Chemie International Edition 51

Version of Record online: 11 APR 2012 | DOI: 10.1002/anie.201200364

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New alkaline-earth amido complexes catalyze the regioselective intermolecular hydroamination (see scheme; Ae=alkaline earth) and hydrophosphination of styrene and isoprene with unprecedented activities. The catalytic performances increased linearly with the size of the metal.

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