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Dr. Yue Zou, Changming Ding, Lijun Zhou, Dr. Zhiming Li, Prof. Dr. Quanrui Wang, Prof. Dr. Franziska Schoenebeck and Dr. Andreas Goeke Tandem Cross-Dimerisation/Oxonia-Cope Reaction of Carbonyl Compounds to Homoallylic Esters and Lactones Angewandte Chemie International Edition 51

Version of Record online: 26 APR 2012 | DOI: 10.1002/anie.201200425

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Conceptually different: This allyltransfer reaction is catalyzed by Lewis acids (LAs) and proceeds atom-economically by disproportionation of the carbonyl groups through organized oxonia-Cope transition states (see scheme). A stereoselective [n+4] ring enlargement leads to a variety of macrolides with 9- to 16-membered rings.

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