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Dr. Sang Ho Lim, Yongxuan Su and Prof. Dr. Seth M. Cohen Supramolecular Tetrahedra of Phosphines and Coinage Metals Angewandte Chemie International Edition 51

Version of Record online: 5 APR 2012 | DOI: 10.1002/anie.201200730

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Treasure chests: The Group 11 metals CuI, AgI, and AuI form tetrahedral supramolecular clusters with a rigid threefold-symmetric phosphine ligand. These supramolecular clusters, which assemble by metal–phosphine interactions, are the first to form across an entire group of the periodic table. Cu+ green, Ag+ pale blue, Au+ green, I red, P purple.

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