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Dr. Tia Jacobs, Rob Clowes, Prof. Andrew I. Cooper and Dr. Michaele J. Hardie A Chiral, Self-Catenating and Porous Metal–Organic Framework and its Post-Synthetic Metal Uptake Angewandte Chemie International Edition 51

Version of Record online: 5 APR 2012 | DOI: 10.1002/anie.201200758

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Free vacancies: A robust and porous metal–organic framework material with unique 4-connected self-catenating structure of {85⋅10} topology was synthesized. The structure features empty bipyridine metal-chelating sites that can be doped with copper cations in a single-crystal-to-single-crystal post-synthetic modification (see picture; scale bar 20 μm).

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