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Sandra Nunige, Dr. Renaud Cornut, Dr. Hassan Hazimeh, Dr. Fanny Hauquier, Prof. Dr. Christine Lefrou, Dr. Catherine Combellas and Dr. Frédéric Kanoufi Reactivity of Surfaces Determined by Local Electrochemical Triggering: A Bromo-Terminated Self-Assembled Monolayer Angewandte Chemie International Edition 51

Version of Record online: 12 APR 2012 | DOI: 10.1002/anie.201201083

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Magic ink: The chemical reactivity of a bromo-terminated self-assembled monolayer immobilized on an insulating substrate is quantified from the time evolution of patterns formed during the local reduction of the SAM (see picture; bpy=2,2′-bipyridine). The potential of this lithographic strategy to determine the reactivity of the self-assembled monolayer is described and compared to surface interrogation by electrochemical microscopy.

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