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Prof. Dr. Horst Kisch Semiconductor Photocatalysis—Mechanistic and Synthetic Aspects Angewandte Chemie International Edition 52

Article first published online: 4 DEC 2012 | DOI: 10.1002/anie.201201200

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Photoinduced charge generation at semiconductor surfaces is currently the most promising method for the chemical utilization of visible light. These charges can be utilized for catalytic redox processes such as nitrogen fixation, functionalization of alkanes, and linear addition reactions of olefins to 1,2-diazenes and imines. Semiconductor photocatalysis combines aspects of classical photochemistry with electrochemistry, solid-state chemistry, and heterogeneous catalysis.

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