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Santanu Sarkar, Dr. Elena Bekyarova and Prof. Robert C. Haddon Reversible Grafting of α-Naphthylmethyl Radicals to Epitaxial Graphene Angewandte Chemie International Edition 51

Version of Record online: 5 APR 2012 | DOI: 10.1002/anie.201201320

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The Kolbe electrochemical oxidation strategy has been utilized to achieve an efficient quasireversible electrochemical grafting of the α-naphthylmethyl functional group to graphene. The method facilitates reversible bandgap engineering in graphene and preparation of electrochemically erasable organic dielectric films. The picture shows Raman D-band maps of both systems.

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