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Prof. Shusaku Nagano, Yusuke Koizuka, Tomoya Murase, Masami Sano, Prof. Yuya Shinohara, Prof. Yoshiyuki Amemiya and Prof. Takahiro Seki Synergy Effect on Morphology Switching: Real-Time Observation of Photo-Orientation of Microphase Separation in a Block Copolymer Angewandte Chemie International Edition 51

Version of Record online: 25 MAY 2012 | DOI: 10.1002/anie.201201346

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Light, (CCD) camera, action! Time-resolved synchrotron X-ray scattering measurements revealed that linear polarized light (LPL) caused reorientation of phase-separated mesoscopic amorphous cylinders within a light-responsive liquid crystalline (LC) matrix domain of a diblock copolymer (see scheme). Cooperative and synchronized motions occur at two hierarchical structures of the LC layer (molecular level) and the polymer domains (mesoscopic level).

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