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Scott P. Semproni, Carsten Milsmann and Paul J. Chirik Structure and Reactivity of a Hafnocene μ-Nitrido Prepared From Dinitrogen Cleavage Angewandte Chemie International Edition 51

Article first published online: 5 APR 2012 | DOI: 10.1002/anie.201201361

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Carbonylation of the strongly activated hafnocene dinitrogen complex, [{(η5-C5H2-1,2,4-Me3)2Hf}2222-N2)], in the presence of electron-rich 4-substituted pyridines resulted in isolation of rare μ-nitrido hafnocene complexes prepared from N2 cleavage. The electronic and molecular structures as well as the intermediacy in N[BOND]C bond forming reactions has been determined.

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