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Dr. Victor Blanco, Dr. Armando Carlone, Dr. Kevin D. Hänni, Prof. David A. Leigh and Dr. Bartosz Lewandowski A Rotaxane-Based Switchable Organocatalyst Angewandte Chemie International Edition 51

Version of Record online: 13 APR 2012 | DOI: 10.1002/anie.201201364

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Switch it on! The activity of an organocatalytic group incorporated within a rotaxane architecture can be controlled by switching the position of the macrocycle. The system was used to mediate the progress of the Michael addition of an aliphatic thiol to trans-cinnamaldehyde.

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