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Ying Xia, Zhenxing Liu, Qing Xiao, Peiyuan Qu, Rui Ge, Dr. Yan Zhang and Prof. Dr. Jianbo Wang Rhodium(II)-Catalyzed Cyclization of Bis(N-tosylhydrazone)s: An Efficient Approach towards Polycyclic Aromatic Compounds Angewandte Chemie International Edition 51

Version of Record online: 24 APR 2012 | DOI: 10.1002/anie.201201374

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Ahead of the PAC: Polycyclic aromatic compounds (PACs) can be easily accessed by the combination of Suzuki–Miyaura cross-coupling and a [Rh2(OAc)4]-catalyzed carbene reaction using easily available bis(N-tosylhydrazone)s as intermediates (see scheme; Ts=4-toluenesulfonyl).

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