E-mail a Wiley Online Library Link

Dr. Bo Yao, Dr. Qian Wang and Prof. Dr. Jieping Zhu Palladium(II)-Catalyzed Intramolecular Diamination of Alkynes under Aerobic Oxidative Conditions: Catalytic Turnover of an Iodide Ion Angewandte Chemie International Edition 51

Version of Record online: 12 APR 2012 | DOI: 10.1002/anie.201201640

Thumbnail image of graphical abstract

“I” did it: A sequential intramolecular amination/N-demethylation/amidation of internal acetylenes in the presence of a catalytic amount of Pd(OAc)2 and nBu4NI afforded indolo[3,2-c]isoquinolinones under mild aerobic conditions (see scheme, DMSO=dimethyl sulfoxide). The iodide ion was regenerated by reaction of in situ generated MeI with HOAc present in the reaction mixture.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field