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Markus A. Reichle and Prof. Dr. Bernhard Breit Preparation of Alkylmagnesium Reagents from Alkenes through Hydroboration and Boron–Magnesium Exchange Angewandte Chemie International Edition 51

Article first published online: 23 APR 2012 | DOI: 10.1002/anie.201201704

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Tolerant: Alkylmagnesium reagents can be synthesized from alkenes through a sequence of hydroboration and subsequent boron–magnesium exchange using a method that tolerates different functional groups (see scheme). The resulting alkylmagnesium reagents can be used in carbon–carbon bond forming reactions, such as alkylation reactions or transition-metal-catalyzed cross-coupling reactions.

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