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Christina Sun, Zachary M. Hudson, Leanne D. Chen and Prof. Dr. Suning Wang Double Cyclization/Aryl Migration Across an Alkyne Bond Enabled by Organoboryl and Diarylplatinum Groups Angewandte Chemie International Edition 51

Version of Record online: 26 APR 2012 | DOI: 10.1002/anie.201201781

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Synergy between metals: Diarylacetylenes 1, containing both a boryl (BMes2) group and a diarylplatinum group, undergo a transformation involving a double metallocyclization/aryl migration to give tetracycles 2 in high diastereoselectivity (see scheme). This remarkable transformation is enabled by the synergistic interplay of the boryl and the diarylplatinum group.

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