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Dr. Da-Peng Dong, Prof. Tao Liu, Dr. Shinji Kanegawa, Dr. Soonchul Kang, Prof. Osamu Sato, Prof. Cheng He and Prof. Chun-Ying Duan Inside Cover: Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain (Angew. Chem. Int. Ed. 21/2012) Angewandte Chemie International Edition 51

Article first published online: 15 MAY 2012 | DOI: 10.1002/anie.201202782

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A cooperative, reversible charge-transfer-induced spin transition that occurs upon cooling and heating of the well-isolated cyanide-bridged FeIII2CoII double-zigzag chain {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2}⋅2H2O⋅2CH3OH (pzTp=tetrakis(pyrazolyl)borate) is described in the Communication by T. Liu, O. Sato, C.-Y. Duan et al. on page 5119 ff. Irradiation of the chain with 532 nm light at 5 K results in a single-chain magnetic behavior with no antiferromagnetic ordering after the irradiation.

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