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Shunyou Cai, Xinyang Zhao, Xinbo Wang, Qisong Liu, Prof. Dr. Zigang Li and Prof. Dr. David Zhigang Wang Visible-Light-Promoted C[BOND]C Bond Cleavage: Photocatalytic Generation of Iminium Ions and Amino Radicals Angewandte Chemie International Edition 51

Version of Record online: 3 JUL 2012 | DOI: 10.1002/anie.201202880

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Photoscissors: Structurally variable and synthetically robust iminium ions and amino radicals species could be simultaneously generated by visible-light-promoted photoredox cleavage of the C[BOND]C bonds in simple vicinal diamine precursors under very mild reaction conditions.

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