Hiroto Noda, Dr. Ken Motokura, Dr. Akimitsu Miyaji and Prof. Dr. Toshihide Baba Heterogeneous Synergistic Catalysis by a Palladium Complex and an Amine on a Silica Surface for Acceleration of the Tsuji–Trost Reaction Angewandte Chemie International Edition 51
The cooperative surface-catalysis strategy of a Brønsted acid and an organic base can be extended to a metal complex and organic base pair. A silica-supported diaminopalladium complex and a tertiary amine were prepared and characterized. The Pd-catalyzed Tsuji–Trost reaction was enhanced significantly by the presence of the tertiary amine on the same silica surface as the Pd complex.
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