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Dr. Terutsune Osawa, Dr. Takashi Kajitani, Dr. Daisuke Hashizume, Dr. Hiroyuki Ohsumi, Dr. Sono Sasaki, Prof. Dr. Masaki Takata, Dr. Yoshiko Koizumi, Dr. Akinori Saeki, Prof. Dr. Shu Seki, Prof. Dr. Takanori Fukushima and Prof. Dr. Takuzo Aida Wide-Range 2D Lattice Correlation Unveiled for Columnarly Assembled Triphenylene Hexacarboxylic Esters Angewandte Chemie International Edition 51

Version of Record online: 29 JUN 2012 | DOI: 10.1002/anie.201203077

Thumbnail image of graphical abstract

Dipole bridge: Liquid-crystalline (LC) triphenylenes (see picture) self-assemble columnarly into a hexagonal geometry with a wide-range 2D lattice correlation, for which distal and proximal dipole–dipole interactions are considered responsible. By virtue of the strong intercolumnar interaction, the LC columns of the triphenylene can spontaneously align homeotropically on the 12 different substrates examined (POM=polarized optical microscopy).

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