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Dr. Paul Könst, Dr. Hedda Merkens, Dr. Selin Kara, Svenja Kochius, Dr. Andreas Vogel, Dr. Ralf Zuhse, Dr. Dirk Holtmann, Prof. Dr. Isabel W. C. E. Arends and Dr. Frank Hollmann Enantioselective Oxidation of Aldehydes Catalyzed by Alcohol Dehydrogenase Angewandte Chemie International Edition 51

Version of Record online: 31 AUG 2012 | DOI: 10.1002/anie.201203219

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Teaching old dogs new tricks: Alcohol dehydrogenases (ADHs) may be established redox biocatalysts but they still are good for a few surprises. ADHs can be used to oxidize aldehydes, and this was demonstrated by the oxidative dynamic kinetic resolution of profens. In the presence of a suitable cofactor regeneration system, this reaction can occur with high selectivity.

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