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Dr. Qing-Lun Wang, Heather Southerland, Dr. Jian-Rong Li, Dr. Andrey V. Prosvirin, Dr. Hanhua Zhao and Prof. Dr. Kim R. Dunbar Crystal-to-Crystal Transformation of Magnets Based on Heptacyanomolybdate(III) Involving Dramatic Changes in Coordination Mode and Ordering Temperature Angewandte Chemie International Edition 51

Article first published online: 15 AUG 2012 | DOI: 10.1002/anie.201203309

Thumbnail image of graphical abstract

Two for one: Two unusual magnets based on the [Mo(CN)7]4− building block with MnII linkers have been prepared with different topological 3D networks. Conversion of one into the other is triggered by dehydration during a single-crystal to single-crystal event (see picture; Mn: dark red, Mo: pink, C: green, N: blue, O: red).

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