Dr. Florian Kessler, Basile F. E. Curchod, Dr. Ivano Tavernelli, Prof. Ursula Rothlisberger, Dr. Rosario Scopelliti, Dr. Davide Di Censo, Prof. Michael Grätzel, Dr. Md. Khaja Nazeeruddin and Dr. Etienne Baranoff A Simple Approach to Room Temperature Phosphorescent Allenylidene Complexes Angewandte Chemie International Edition 51
A warm (blue) glow: A stable bis-cyclometalated iridium(III) allenylidene complex is prepared from a bis-cyclometalated iridium(III) complex (see scheme). This strategy gives the first allenylidene complex that is phosphorescent at room temperature.
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