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Deepthi Jose and Prof. Dr. Ayan Datta Tunneling Governs Intramolecular Proton Transfer in Thiotropolone at Room Temperature Angewandte Chemie International Edition 51

Version of Record online: 15 AUG 2012 | DOI: 10.1002/anie.201203355

Thumbnail image of graphical abstract

Successfully tunneled: The rapid and temperature-independent intramolecular proton transfer in thiotropolone occurs entirely through quantum mechanical tunneling (see picture). For tropolone, tunneling across a smaller yet broader barrier leads to a slower rate of proton transfer for temperatures smaller than 240 K.

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