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Xiaoliang Liang, Jie Li, Dr. Ji Bong Joo, Dr. Alejandro Gutiérrez, Dr. Aashani Tillekaratne, Dr. Ilkeun Lee, Prof. Yadong Yin and Prof. Francisco Zaera Diffusion through the Shells of Yolk–Shell and Core–Shell Nanostructures in the Liquid Phase Angewandte Chemie International Edition 51

Article first published online: 29 JUN 2012 | DOI: 10.1002/anie.201203456

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Easy in, easy out: Mass transport through TiO2 and SiO2 shells was probed in the liquid phase with IR spectroscopy by detecting carbon monoxide adsorption in Pt@void@TiO2 yolk–shell and Pt@SiO2 core–shell nanostructures (see picture; C green, O red, Pt pale red). Adsorption was observed on the surface of Pt nanoparticle cores, and on the inner face of the TiO2 shells in the yolk–shell case.

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