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Jerome R. Robinson, Dr. Patrick J. Carroll, Prof. Patrick J. Walsh and Prof. Eric J. Schelter The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry Angewandte Chemie International Edition 51

Article first published online: 31 AUG 2012 | DOI: 10.1002/anie.201203481

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Let's get cerium: The role of ligand organization in the redox chemistry of CeIII was investigated with a series of cerium(III)/alkali metal/1,1′-binolate (REMB) complexes. The electrochemical properties and chemical reactivity within the REMB framework are tunable through the choice of metal M, and the controlled redox behavior emphasizes the impact of ligand reorganization.

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