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Dr. Yoshihiro Nishimoto, Hiroki Ueda, Dr. Makoto Yasuda and Prof. Dr. Akio Baba Gallium Tribromide Catalyzed Coupling Reaction of Alkenyl Ethers with Ketene Silyl Acetals Angewandte Chemie International Edition 51

Version of Record online: 2 JUL 2012 | DOI: 10.1002/anie.201203778

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A ‘Ga'llant couple: The α-alkenylation of esters was accomplished by GaBr3-catalyzed coupling between alkenyl ethers and ketene silyl acetals. In this reaction system, various alkenyl ethers, including those with vinyl and substituted alkenyl groups, were applicable, and the scope of applicable ketene silyl acetals was sufficiently broad. The mechanism is also discussed.

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