Kine Ø. Hanssen, Bruno Schuler, Dr. Antony J. Williams, Taye B. Demissie, Dr. Espen Hansen, Dr. Jeanette H. Andersen, Dr. Johan Svenson, Kirill Blinov, Dr. Michal Repisky, Dr. Fabian Mohn, Dr. Gerhard Meyer, Prof. Dr. John-Sigurd Svendsen, Prof. Dr. Kenneth Ruud, Prof. Dr. Mikhail Elyashberg, Dr. Leo Gross, Prof. Dr. Marcel Jaspars and Dr. Johan Isaksson A Combined Atomic Force Microscopy and Computational Approach for the Structural Elucidation of Breitfussin A and B: Highly Modified Halogenated Dipeptides from Thuiaria breitfussi Angewandte Chemie International Edition 51
Article first published online: 26 OCT 2012 | DOI: 10.1002/anie.201203960
Turning a new leaf: The first structures isolated from Thuiaria breitfussi, the breitfussins, are presented. This structural class consists of indole–oxazole–pyrrole units. Limited quantities prevented crystallization; therefore, the structures were solved using a novel combination of AFM, computer-aided structure elucidation (CASE), and DFT calculations. Visualization by AFM determined all the connection points of the cyclic systems and the other substituents.
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