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Prof. Dr.  A. Stephen K. Hashmi, M. Sc. Marcel Wieteck, Dr. Ingo Braun, Dr. Matthias Rudolph and Dr. Frank Rominger Gold Vinylidene Complexes: Intermolecular C(sp3)[BOND]H Insertions and Cyclopropanations Pathways Angewandte Chemie International Edition 51

Version of Record online: 17 SEP 2012 | DOI: 10.1002/anie.201204015

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Highly reactive gold vinylidene species are used for intermolecular C(sp3)[BOND]H insertions into unactivated alkanes (see scheme). In addition, they can be regarded as synthons for alkylidene carbenes. Initiated by cyclopropanation of the vinylidene species/alkylidene carbenoide, cyclobutene derivatives are formed in a diastereoselective fashion by a ring-enlargement cascade in only one step.

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