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Somenath Garai, Dr. Erhard T. K. Haupt, Dr. Hartmut Bögge, Dr. Alice Merca and Prof. Dr. Achim Müller Picking up 30 CO2 Molecules by a Porous Metal Oxide Capsule Based on the Same Number of Receptors Angewandte Chemie International Edition 51

Version of Record online: 24 SEP 2012 | DOI: 10.1002/anie.201204089

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30 receptors in waiting position: In the porous (pentagon)12(linker)30-type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO32− ligands) can act as receptors for neutral and negatively charged ligands. Bubbling CO2 into the solution containing the acetate-type capsules leads to the upload of CO2 based on 30 coordinated CO32− ligands.

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